𝔖 Bobbio Scriptorium
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Binding of copper and zinc ions to polypeptides containing glutamic acid and tyrosine residues

✍ Scribed by A. Béré; C. Hélène


Book ID
119069583
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
484 KB
Volume
1
Category
Article
ISSN
0141-8130

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## Abstract Metal ions such as Zn^2+^ and Cu^2+^ can mediate interactions between copolypeptides (Glu~__x__~, Tyr~__y__~)~__n__~ and polynucleotides. CD data show that these ternary complexes are characterized by an unstacking of nucleic acid bases, while the polypeptide adopts an α‐helical conform

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## Abstract Six sequential polytetrapeptides containing equimolar amounts of tyrosine, glutamic acid, alanine, and glycine were characterized by CD and difference spectroscopy over a wide range of pH. As the pH was lowered from physiological values, each of the polymers underwent pH‐sensitive trans