Binding of an Acetic Acid Ligand to Adenosine: A Low-Temperature NMR Study
✍ Scribed by Basílio Janke, Eline M.; Limbach, Hans-Heinrich; Weisz, Klaus
- Book ID
- 120429377
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 143 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Proton NhlR spectra of trimethyl acetic acid, dissolved in a bkoic acid type nematic liquid crystal, have been ~meakued and analysed. making use of the hydrogen bonding capabilities of this sort of nematic phase appears to be an excellent method to obtain very high soiute orientations.
NMR experiments were performed on the association of the two sugar-protected nucleosides 2 -deoxy-4-thiouridine and 2 -deoxyadenosine in solution. Using an aprotic CDClF 2 -CDF 3 solvent mixture, low-temperature measurements allowed the observation of individual hydrogen-bonded complexes in the slow