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Binding energies and stabilities of chloronium ions from study of the gas-phase equilibriums: R1+ + ClR2 = R1ClR2+

✍ Scribed by Sharma, Dilip K. Sen; Kebarle, Paul


Book ID
126311423
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
594 KB
Volume
100
Category
Article
ISSN
0002-7863

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The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/