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Binary Alloys of 2,5-Disubstituted DCNQI Radical Anion Salts of Copper and Their Electrical Conductivity

✍ Scribed by Dr. Peter Erk; Prof. Dr. Siegfried Hünig; Dipl.-Chem. Hubert Meixner; Dipl.-Phys. Hans-Jörg Gross; Dipl.-Phys. Uwe Langohr; Dr. Hans-Peter Werner; Dr. Jost Ullrich von Schütz; Prof. Dr. Hans Christoph Wolf


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
260 KB
Volume
28
Category
Article
ISSN
0044-8249

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✦ Synopsis


8] Thls nomenclature proposal corresponds to the term "pentaphyrin". introduced by Rerhausen and Gossauer [9], for porphyrin-like cyclic pentapyrroles. Accordingly, the porphyrinogen analogues of cyclic pentapyrroles are called "pentaphyrinogens". Since 10 differs from these in the inversion of the five pyrrole rings, it is called an "inverto-pentaphyrinogen".


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2,5-Disubstituted N,N′-Dicyanobenzoquino
✍ Siegfried Hünig; Martina Kemmer; Hubert Meixner; Klaus Sinzger; Hermann Wenner; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 556 KB

The new members of the series of 2,5-disubstituted DCNQIs, temperatures, except [1d (Cl/OMe)] 2 Cu which undergoes a sharp phase transition to an insulating state[M Ǟ I]. By 1d (Cl/OMe), 1e (Br/OMe), 1j (Cl/I), 1k (Br/I), 1l (I/I), form conducting charge-transfer complexes with TTF variation of the