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Bimolecular substitution-fragmentation. Reaction of phenylmethanesulfonyl halides with halide ion

โœ Scribed by King, James Frederick.; Smith, David J. H.


Book ID
126271778
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
289 KB
Volume
89
Category
Article
ISSN
0002-7863

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The ways in which nucleophiles may react with cation radicals have recently been discussed in terms of the Dewar-Zimmerman rules. 3-6 A nucleophile which adds either slowly or not at all to a cation radical is thought to be forbidden by symmetry properties from undergoing bond-forming orbital over