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Bimolecular reactions of trapped ions: Part XI. Rates and equilibria in proton-transfer reactions of CH3SH+2

✍ Scribed by B.H. Solka; A.G. Harrison


Publisher
Elsevier Science
Year
1975
Weight
621 KB
Volume
17
Category
Article
ISSN
0020-7381

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Bimolecular reactions of distonic ions:
✍ Philippe Mourgues; Henri Edouard Audier; Danielle Leblanc; Steen Hammerum πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 314 KB

The bimolecular reaction of 'CH20H2+ with a variety of neutral molecules in the gas phase were studied by Fourier transform ion cyclotron resonance experiments. The distonic ion is found to be considerably more acidic than protonated methanol; bracketing experiments provide a value of 695 8 kJ mol-'