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Bimolecular interactions in the excited state. Hydroxy and aminobenzophenone as sensitizers and quenchers of biacetyl phosphorescence

✍ Scribed by G. Favaro


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
438 KB
Volume
23
Category
Article
ISSN
0009-2614

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✦ Synopsis


which includes a self-quenching of benzophenone triplet and n back transfer from the acceptor to the donor. The kinetic rate constants for these IWO proccsscs have been determined along with the triplet lifetimes and yields of para-amino and pun-hydrosybcnzophenone in benzene at infinite dilution.


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Time-resolved and steady state equations for successive singlet and triplet quenching by the same quencher in micelles are developed. The model assumes that: (i) the quencher can distribute between micellar and aqueous phases, (ii) the probe is completely micellized, and (iii) the distribution kinet