✦ LIBER ✦

Bimetallic Pt-Co catalysis on carbon nanotubes for the selective hydrogenation of cinnamaldehyde to cinnamyl alcohol: Preparation and characterization

✍ Scribed by Yan Li; Zhen-Guo Li; Ren-Xian Zhou

Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 662 KB
Volume: 279
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2007.10.015

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✦ Synopsis

Carbon nanotubes (CNTs)-based Pt-Co catalysts are prepared by different impregnation techniques and different reduction methods (H 2 , HCHO and KBH 4 ) for the selective reduction of cinnamaldehyde (CMA) to the corresponding cinnamyl alcohol (CMO). The selectivity and activity of the Pt-Co/CNTs catalysts can be improved significantly by using ammonia as a ligand and KBH 4 as a reducing agent because of the synergetic effect of Pt-Co-B. Furthermore, the hydrogenation rate of CMA increases ulteriorly in the presence of trace base and acid promoters.

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