## Abstract Deprotonation of Ap\*H {Ap\*H = (2,6‐diisopropylphenyl)‐[6‐(2,4,6‐triisopropylphenyl)pyridin‐2‐yl]amine} and Ap'H {Ap'H = (2,6‐diisopropylphenyl)‐[6‐(2,6‐dimethylphenyl)pyridin‐2‐yl]amine} using KH leads to polymeric [Ap\*K]__~n~__ and [Ap'K]__~n~__ which undergo clean salt metathesis r
Bimetallic Complexes of Ytterbium and Europium Stabilized by Sterically Demanding Dipyridylamides
✍ Scribed by Anna M. Dietel; Christian Döring; Germund Glatz; Mikhail V. Butovskii; Oleg Tok; Falko M. Schappacher; Rainer Pöttgen; Rhett Kempe
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 582 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The synthesis and characterisation of the homoleptic transition‐metal complexes (1,8‐Ph~2~‐3,6‐Me~2~C~12~H~4~N)~2~M (M = Cr, 1; M = Mn, 2; M = Fe, 3; M = Co, 4) are described. Formally two‐coordinate, the solid‐state structures of 2 and 3 reveal near‐linear N–M–N geometries and signific
## Abstract The sterically hindered benzamidinate ligand [PhC(NAr)~2~]^–^ (Ar = 2,6‐__i__Pr~2~C~6~H~3~) has been employed to prepare bis(amidinate) complexes [{PhC(NAr)~2~}~2~M] of the divalent first‐row transition metals Cr–Ni (1–5). For Cr (planar), Mn and Co (tetrahedral) the observed structures