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Bile acids. LXIV. Synthesis of 5α-cholestane-3α,7α,25-triol and esters of new 5α-bile acids

✍ Scribed by S.V. Hiremath; William H. Elliott


Book ID
118978859
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
622 KB
Volume
38
Category
Article
ISSN
0039-128X

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📜 SIMILAR VOLUMES


Bile acids. LXXI. A new synthesis of (25
✍ Daniel M. Tal (2); William H. Elliott; Edward A. Doisy 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 French ⚖ 313 KB

## Abstract Tritiation of 7‐oxo‐5‐cholestene‐3β,26‐diol diacetate afforded a mixture of [5α,6α‐^3^H~2~] products which were reduced with lithium aluminum hydride to provide a mixture of [5α,6α‐^3^H~2~]‐3β, (7α and 7β), 26‐triols an 3β, 26‐diol. Oxidation with Jones reagent provided 3,7‐dioxo and 3‐

Bile alcohol glucuronides: regioselectiv
✍ Bishambar Dayal; Gerald Salen; Janak Padia; Sarah Shefer; George S. Tint; Gino S 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 746 KB

## ABSTRAm A facile and regiocontrolled procedure for the preparation of S~-cholestane-3a,7c,l2~,25-tetrol-3-O-fi-o-glucuronide and its corresponding C-26 analogue is described. The method involves direct coupling of bile alcohols, namely, 5/3-cholestane-3rY,7~,12a,25-tetrol and 24-nor-Sp-cholesta