Bildung und Struktur von [μ-(1,2 : 2-η-tBu2P–P){Mo(CO)2cp′}2]

✍ Scribed by Harald Krautscheid; Eberhard Matern; Jolanta Olkowska-Oetzel; Jerzy Pikies; Gerhard Fritz

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: German
• Weight: 95 KB
• Volume: 627
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/1521-3749(200107)627:7<1505::aid-zaac1505>3.0.co;2-5

✦ Synopsis

Professor Hansgeorg Schno È ckel zum 60. Geburtstag gewidmet

Coordination Chemistry of P-rich Phosphanes and Silylphosphanes. XXIV. [1] Formation and Structure of [l-(1,2 : 2-g-t Bu 2 P±P){Mo(CO) 2 cp'} 2 ] Abstract. [cp'Mo(CO) 2 ] 2 (cp' = C 5 H 4 t Bu) reacts with t Bu 2 P±P=P(Me) t Bu 2 to yield the compound [l-(1,2 : 2g-t Bu 2 P±P){Mo(CO) 2 cp'} 2 ], which crystallizes in the space group P2 1 2 1 2 1 with a = 1202.42(7), b = 1552.48(8), and c = 1765.3(1) pm.