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Bifunctional catalysis in the condensation of silanols and alkoxysilanes

✍ Scribed by Hsien-Kun Chu; Robert P. Cross; David I. Crossan


Book ID
103225918
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
647 KB
Volume
425
Category
Article
ISSN
0022-328X

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Heterofunctional condensation of alkoxys
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Heterofunctional condensation of alkoxysilanes with silanols may be useful for the synthesis of polysiloxane networks, leading to more definite structures than in the case of hydrolysis of chlorosilanes, provided that secondary reactions are avoided. Using methyltrimethoxysilane or y-aminopropyltrim

Heterofunctional condensation of alkoxys
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AMtract--Heterofunctional condensation ofdialkoxysilanes with dihydroxysiloxanes has been used for the preparation of polysiloxanes of definite structure. The model reaction between N-fl-aminoethyl-~,aminopropylmethyl-dimethoxysilane and a monosilanol (PhMe2SiOH) has been studied by GC and ~H-NMR. T