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Bidentate Phosphines of Heteroarenes: 4,6-Bis(diphenylphosphino)dibenzofuran and 4,6-Bis(diphenylphosphino)dibenzothiophene

✍ Scribed by Haenel, Matthias W. ;Jakubik, Dieter ;Rothenberger, Eveline ;Schroth, Gerhard


Book ID
102789109
Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
649 KB
Volume
124
Category
Article
ISSN
0009-2940

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10-(tert-Butyl­dimethyl­silyl)-4,6-bis­(
✍ Osiński, Piotr W. ;Schürmann, Markus ;Preut, Hans ;Haag, Rainer ;Eilbracht, Pete 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 206 KB

The title compound, C 42 H 41 NOP 2 Si, used as a nixantphos-type ligand in homogeneous catalysis, crystallizes with one molecule in the asymmetric unit. The molecule has nearly mirror symmetry with N, O and Si on the pseudo-mirror plane, but it is not located on a crystallographic mirror plane. The