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Bicyclo[3,3,1]nonan-2-ol from 4-Cyclooctenylmethyl Toluenesulfonate

โœ Scribed by Doz. Dr. M. Hanack; Dipl.-Chem. W. Kaiser

Publisher
John Wiley and Sons
Year
1964
Tongue
English
Weight
126 KB
Volume
3
Category
Article
ISSN
0044-8249

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โœฆ Synopsis

the latter are only weakly basic owing to the electron attraction of the triple bond. The quaternary N-alkynylammonium salt which is presumably initially formed from triethylene diainine and phenylchloroacetylene can condense in a subsequent reaction with a further mole of tertiary amine [61 to form 12).

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Stereoselective reduction of (ยฑ)-bicyclo
Stereoselective reduction of (ยฑ)-bicyclo[3.3.1]nonane-2,6-dione by microorganisms
โœ Mitsuo Miyazawa; Masahiro Nobata; Shigeaki Okamura; Osamu Muraoka; Genzoh Tanabe ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 277 KB ๐Ÿ‘ 1 views

The biotransformation of (^)-bicyclo [3.3.1]nonane-2,6-dione by Aspergillus niger and Glomerella cingulata was investigated. The diketone was reduced to the ketoalcohol 2-endo-hydroxy-bicyclo[3.3.1]nonane-6-one and the diol endo,endo-bicyclo[3.3.1]nonane-2,6-diol respectively. Endo,endobicyclo[3.3.1