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Bicyclo[2.2.1]hepta-2, 5-dien-7-spirocyclobutan

✍ Scribed by Armin de Meijere; Lüder-Ulrich Meyer


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
220 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


Die elektronische Wechselwirkung zwischen einem p-Orbital in eines Bicyclo[2.2.1]heptadiensystems und den n-Orbitalen der durch den Raum zeigt sich besonders an der auBergew8hnlichen r3i der 7-Stellung Doppelbindungen StabilitZt des No. 24 Anmerkunqen und Literatur [: 'I c 11 c 21 c 31


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Photoinduced addition of nucleophiles to
✍ Paul G. Gassman; Kurt D. Olson 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 251 KB

The l-cyanonaphthalene photosensitized addition of water and methanol to the cation-radical of bicyclo[2.2.1]hepta-2,5-diene is described. Recently, we demonstrated that nucleophiles could be added across strained carbon-carbon sigma bonds in photosensitized reactions which are readily interpreted