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Bicyclo[1.1.1]pentane from mercury sensitized and unsensitized gas phase photolyses of bicyclo[2.1.1]hexan-2-one

โœ Scribed by Jerrold Meinwald; William Szkrybalo; Donald R. Dimmel


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
185 KB
Volume
8
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The impact of photochemical techniques on the synthesis of small ring compounds would be difficult to overestimate.


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On the hydroxylation of bicyclo[2.1.0]pe
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The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mecha