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BiCo heteronuclear carbonyl compounds. Synthesis of the anion [Bi{Co(CO)4}4]− and X-ray crystal structure of its tetramethylammonium salt

✍ Scribed by Secondo Martinengo; Alessandro Fumagalli; Gianfranco Ciani; Massimo Moret


Book ID
107811087
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
739 KB
Volume
347
Category
Article
ISSN
0022-328X

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✍ Kirill Yu. Monakhov; Thomas Zessin; Gerald Linti 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 648 KB

## Abstract The reaction of __cyclo__‐Bi~4~[Si(SiMe~3~)~3~]~4~ (1) with Na~2~[Fe(CO)~4~] in the presence of __n__Bu~4~NCl leads to the formation of the cage compound [__n__Bu~4~N]~4~[Bi~4~Fe~8~(CO)~28~] (2). According to X‐ray single‐crystal structure analysis, the faces of the tetrahedral Bi~4~ co