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Biaryl Synthesis via Palladium-Catalyzed Aryne Multicomponent Coupling

✍ Scribed by Henderson, Jaclyn L.; Edwards, Andrew S.; Greaney, Michael F.

Book ID: 127154777
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 113 KB
Volume: 9
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol702584t

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Unsymmetrical biaryls bearing electron-donating and electron-withdrawing functional groups have been obtained in an efficient manner by Pd-catalyzed coupling of aryl halides. Aryl bromides react with aryl iodides to yield unsymmetrical biaryls with marked selectivity.

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