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Berechnung von freien Hydratationsenthalpien und Koordinationszahlen für Kationen aus leicht zugänglichen Parametern

✍ Scribed by W. E. Morf; W. Simon


Publisher
John Wiley and Sons
Year
1971
Tongue
German
Weight
856 KB
Volume
54
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A model for the computation of free energies of hydration and coordination numbers of cations using easily available parameters is described. For 27 mono‐, di‐ and trivalent cations the mean deviation of the calculated from the experimental Δ__G__°~H~ values is 3.9%. All the computed coordination numbers agree with experimental ones.