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Benzyl ions in the mass spectra of fluoro n-alkylbenzenes

✍ Scribed by S. Majeti; D.A. Lightner

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
170 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

The question of benzyl vs tropylium structures for ions of the general formula XC7H6+ has received renewed attention recently in the electron impact mass spectra of nitrobenzyl compounds (l), bibenzyls (Z), benzyl phenyl ethers (1,3,4), and n-butylbenzenes (5). Evidence for benzyl ion structures has been presented in those cases; whereas, the commonly accepted structure for C7H7+ and related ions is a symmetrical (tropylium) ion ( ). In studies on deuterium and C 13 -

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