In the molecule of the title compound, C 16 H 9 NO 3 S, the two fused ring systems are each planar and make a dihedral angle of 78.0 (1) with each other. In the crystal structure, intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into chains along the b axis and there are alsostacking inter
✦ LIBER ✦
Benzoxazol-2 (3H)-one and 1,3,4-oxadiazol-2(3H) -one derivatives from substituted enaminones and ketoenamines
✍ Scribed by M. Forchiassin; G. Pitacco; A. Risaliti; C. Russo; E. Valentin
- Book ID
- 112127036
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1983
- Tongue
- English
- Weight
- 340 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0022-152X
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## Abstract 3‐(2‐alkenoyl)‐thiocarbazic acid O‐methyl esters **1** are desulfurated by bromine and the unknown intermediates are transformed by alkali to 5‐(1‐alkenyl)‐1, 3, 4‐oxadiazol‐2(3__H__)‐ones (**2**). This type of oxadiazolone substitution is not realizable by the common ring closure of hy
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