The synthesis of thieno[3,2-clcinnoline is described; this compound gives benzo [3,4]cyclobuta[1,2-blthiophene. ## vapour phase thermolysis of The considerable stability of biphenylene, a system containing fused 4n and (4n+2) ITelectron rings, is associated with the fact that its structure corres
Benzo[3,4 cyclobuta[1,2-b cycloheptatriene and benzo[3,4]cyclobuta[1,2]tropylium cation
โ Scribed by L. Lombardo; D. Wege
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 165 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Recent interest in aromatic analogues of biphenylene in which one benzenoid ring is replaced by five membered 6n electron systemsIs prompts us to report our synthesis of the title triene 5 and the derived tropylium salt 11.
-The latter is a derivative of biphenylene in which a benzenoid ring is replaced by a seven membered 6n electron system. A benzoannellated derivative of 11 has been described recentlyl.
๐ SIMILAR VOLUMES
During recent years, a considerably amount of attention has been devoted to the synthesis of aromatic analogues of biphenylene 1, in which one bensenoid ring is replaced by another (an + 2)x electron system. Compounds which have been prepared include the norbiphenylene anion 2l , benzo[3,4]cyclobuta
Following our synthesis of the benzo[3,4]cyclobutap,2]tropylium cation', we have been actively engaged in investigating routes to the three possible isomeric benzo [3,4]cyclobuta[l,2]troPones 2, 3, and $.
## Syntheses of the benzodicinnolines (3) and ( 4), and their vacuum thermolysis to give the title compound (l), are reported. The effects which arise from the fusion of small, strained rings 192 and of potentially
Current interest in strained systems resulting from the fusion of more than one small, strained ring onto a benzene nucleus has led to the recent synthesis of molecules such as 1,2,5,6-tetrahydrodicyclobuta[a,c]benzene (l).l