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Benzenecarboxylate Surface Complexation at the Goethite (α-FeOOH)/Water Interface: I. A Mechanistic Description of Pyromellitate Surface Complexes from the Combined Evidence of Infrared Spectroscopy, Potentiometry, Adsorption Data, and Surface Complexation Modeling

✍ Scribed by Boily, Jean-François; Nilsson, Nils; Persson, Per; Sjöberg, Staffan

Book ID: 126989924
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 182 KB
Volume: 16
Category: Article
ISSN: 0743-7463
DOI: 10.1021/la991407o

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A surface complexation model describing the adsorption of three benzenecarboxylates (phthalate, trimellitate, and pyromellitate) on goethite (α-FeOOH) was calibrated on data using goethite particles of 37 and 43 m 2 /g surface area. The models predict potentiometric titration and batch adsorption da