Benzene in theμ3-η2:η2:η2-face-capping coordination mode
✍ Scribed by B. F. G. Johnson; P. J. Dyson
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 589 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0340-4285
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## Abstract Reduction potential (__E__~red~) values have been calculated and compared with available cyclic voltammetry (CV) data for 10 metallofullerene complexes with the μ~3~‐η^2^:η^2^:η^2^‐C~60~ (M~3~C~6~[C~60~]) bonding mode. Consideration of bulk solvent effects is essential for the calculat
A few characteristic data of the compounds (1 l ) , (1 2), and ( 14)-( 17) are collected in Table 2. Apart from the diastereomerism caused by the methoxyethyl protecting group in (13), (16a), and (17), the compounds are, according to the IHand I3C-NMR spectra, diastereomerically pure and thus in the