The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma
Benzene- and Toluene-Photosensitized Isomerization of 1,2-Dimethylcyclopropane. The Triplet State of Cyclopropane
✍ Scribed by Bell, Jerry A.
- Book ID
- 127267734
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 368 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi
## Abstract Thermolysis of the “all‐__cis__” compound 1α‐chloro‐2α,3α‐dimethylcyclopropane (A) at 550–607 K and 6–115 torr is a first‐order homogeneous non‐radical‐chain process giving penta‐1,3‐diene (PD) and HCl as products. The Arrhenius parameters are log~10~__A__(sec^−1^) = 13.92 ± 0.08 and __