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Benign approaches for the synthesis of bis-imine Schiff bases

โœ Scribed by van den Ancker, Tania R. ;Cave, Gareth W. V. ;Raston, Colin L.


Book ID
120644383
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
245 KB
Volume
8
Category
Article
ISSN
1463-9262

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## Abstract Terephthalic Schiff bases react with hypophosphorous acid to form 1,4โ€phenyleneโ€bisโ€__N__โ€alkylโ€aminomethanephosphonous acids in moderate yields. NMR studies demonstrated thatโ€”for several examplesโ€”this reaction led to the exclusive formation of only one diastereomeric form. NMR investig