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Bending of the completely conjugated planar macrocyclic iron(II) complex by 1,10-phenanthroline. The crystal structure of [Fe(II)(C18H18N6)(C12H8N2)](ClO4)2

✍ Scribed by You Yuan-Shyane; Peng Shie-Ming


Book ID
108324635
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
213 KB
Volume
192
Category
Article
ISSN
0020-1693

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat