Bending force constants for weakly bound dimers AB (A, symmetric top; B, linear molecule) from gas-phase nuclear quadrupole coupling constants

Bending force constants for weakly bound

Bending force constants for weakly bound dimers AB (A = symmetric top, B = linear molecule) from centrifugal distortion in rotational spectra

✍ A.C. Legon; D.G. Lister 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 490 KB

The contribution of the harmonic intermolecular bending force field to the quartic centrifugal distortion constants of weakly bound dimers Al3 (where A is a symmetric-top molecule and B is a linear molecule) has been examined. Approximate formulae are derived that relate the force constant and the v