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Behavior of Some Inorganic Anions as Bases in Glacial Acetic Acid

✍ Scribed by Higuchi, Takeru ;Concha, Jesusa

Publisher
Elsevier
Year
1951
Weight
179 KB
Volume
40
Category
Article
ISSN
0095-9553

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✦ Synopsis

Data are presented to show that all common inorganic anions, except bisulfate, act as bases in glacial acetic acid. Supporting evidence includes results obtained by titrating a number of alkaloidal salts and many inorganic salts. Theoretical basis for this behavior is discussed.

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A reporting advantages of titrating weak bases in glacial acetic acid and other nonaqueous solvents as compared to their determination in aqueous media (1-4). Aniline, for example, can be titrated readily in glacial acetic acid with perchloric acid, whereas in water such titration leads to indefinite end points. It is evident that

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