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Behavior of 3(3-Indolylmethylene)-5-aryl-2(3H)-furanones as Alkylating Agents: Intra- versus Intermolecular Alkylation.

✍ Scribed by Wael S. I. Abou-Elmagd

Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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Behavior of 3(2-pyridinylmethylene)-5-ar
Behavior of 3(2-pyridinylmethylene)-5-aryl-2(3H)-furanones and 3(3-pyridinylmethylene)-5-aryl-2(3H)-furanones as alkylating agents: A comparative study
✍ Wael S. I. Abou Elmagd 📂 Article 📅 2011 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 256 KB

## Abstract 3(2‐pyridinylmethylene)‐5‐aryl‐2(3__H__)‐furanones and 3(3‐pyridinylmethylene)‐5‐aryl‐2(3__H__)‐furanones were prepared as a mixture of (E) and (Z) stereoisomers by condensing pyridine‐2‐carboxaldehyde and pyridine‐3‐carboxaldehyde with 3‐aroylpropionic acids. The reaction of the furano

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Behavior of 3-benzylamino-5-aryl-2(3H)-furanones towards some nitrogen nucleophiles
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## Abstract magnified image Ring closure of 2‐__N__‐benzylamino‐3‐aroylpropionic acids (**3**) with acetic anhydride afforded 3‐__N__‐benzylamino‐5‐aryl‐2(3__H__)‐furanones (**4**). The reaction of the furanones (**4**) with benzylamine in benzene was found to be time dependent. Thus refluxing the