✦ LIBER ✦
Behavior of [2.n]metacyclophanes-fused cyclobutane ring in bromination
✍ Scribed by Yukihiro Okada; Masanori Yokozawa; Masatoshi Kaneko; Jun Nishimura
- Book ID
- 104251566
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 80 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Dimethoxy[2.2]metacyclophane mainly gave a tetrahydropyrene structure and the other [2.n]metacyclophane derivatives (n=3-5) gave aromatic bromides like pseudo-ipso and/or pseudo-ortho dibromides in the reaction with bromine. They also gave benzyl bromides by cyclobutane ring-opening.