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[Be(dad)2]: Synthesis and Structure of a Diazabutadieneberyllium Complex

✍ Scribed by Prof. Dr. Karl-Heinz Thiele; Dipl.-Chem. Volker Lorenz; Prof. Dr. Gerhard Thiele; Dipl.-Chem. Peter Zönnchen; Dr. Joachim Scholz

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 272 KB
Volume: 33
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199413721

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E, they are also not hydrolyzed by conc. hydrochloric acid. 3a-c can be deprotonated with sodium hydroxide and acylated at the nitrogen. Although in the 1,2,4-diazaphospholes a 1,3-diamino-2phosphaallyl system is still formally present, the ring closure is associated with an essential change: the c