Use of the Wolff Rearrangement of Diazo
✍
Christel Guibourdenche; Dieter Seebach; François Natt
📂
Article
📅
1997
🏛
John Wiley and Sons
🌐
German
⚖ 696 KB
## Abstract Photolysis and Ag‐benzoate‐catalyzed decomposition of the diazo ketones 2 and 4 derived from Z‐Ala‐OH and Z‐Ala‐Ala‐OH in the presence of oligonucleotide derivatives bearing at the 5′‐terminus an NH~2~ instead of the OH group, or an aminohexyl phosphate group lead to Z‐protected 3‐amino