## Abstract Changes in the quantities of active stabilizing components during thermal aging of plasticized poly(vinyl chloride) containing a mixture of calcium and zinc stearates were analyzed. A mathematical model of the stabilization process by using the stabilizer mixture and a computer program
Basic principles of thermal degradation and thermal stabilization of poly(vinyl chloride). Mathematical model of the action of PVC thermal stabilizers
β Scribed by Krzysztof Prochaska; Jerzy Wypych
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 538 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
A model of the action of chemically homogeneous thermal stabilizers of poly(vinyl chloride) is shown. Based on the described computer program and experimental data, the proposed model is confirmed and rate constants of the reaction of stabilizers with HCI and the effect of the products of this reaction on the kinetics of PVC degradation are calculated.
π SIMILAR VOLUMES
The stability of poly(viny1 chloride), as measured by thermogravimetric analysis, is significantly different from that of other thermoplastics. It is shown that the onset of weight loss can be correlated with the development of color in a processed resin. It is further shown that the ingredients wit
An emulsion, poly(vinyl chloride) (PVC), was analyzed for its components and was used in the preparation of flexible PVC plates utilizing sol-gel processing technology. PVC contained an ether-soluble fraction having carboxylic acid carbonyl groups, a tetrahydrofurane (THF)-insoluble fraction having