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Base-promoted reduction of trans-dibromotetracyanoplatinate(IV) and hypobromous acid oxidation of tetracyanoplatinate(II). Kinetics and mechanisms

✍ Scribed by Chandayot, Pongchan; Fanchiang, Yueh Tai

Book ID: 126915837
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 358 KB
Volume: 24
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00216a012

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## Abstract Kinetic studies on the oxidation of 2‐mercaptosuccinic acid by dinuclear [Mn~2~^III/IV^(μ‐O)~2~(cyclam)~2~](ClO~4~)~3~] (1) (abbreviated as Mn^III^–Mn^IV^) (cyclam = 1,4,8,11‐tetraaza‐cyclotetradecane) have been carried out in aqueous medium in the pH range of 4.0–6.0, in the presence o