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Base-Promoted Reaction of 5-Hydroxyuracil Derivatives with Peroxyl Radicals

✍ Scribed by Amorati, Riccardo; Valgimigli, Luca; Pedulli, Gian Franco; Grabovskiy, Stanislav A.; Kabal’nova, Natalia N.; Chatgilialoglu, Chryssostomos


Book ID
111657585
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
410 KB
Volume
12
Category
Article
ISSN
1523-7060

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Absolute rate constants for the one electron oxidation of guanine, guanosine, uric acid, xanthine, hypoxanthine, tyrosine, and thymine by various halogenated peroxyl radicals in aqueous solutions have been determined using the technique of pulse radiolysis. Roughly, linear correlations have been obs