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Base-initiated elimination reactions of N-arylsulfonoxysulfonamides

✍ Scribed by Mitsuo Okahara; Daniel Swern

Book ID: 104239741
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 207 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88415-x

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✦ Synopsis

Received in USA 7 May 1969; received in IK for publication 16 July 1969) . . Nitrenes are neutral, electrophilic species, R-.;, isoelectronic with carbenes and they show similar reactivity (l-4). Photolysis and thermolysis of azides are the most important nitrene-generating methods and have been used, for example, to obtain carboalkoxynitrenes (3,4) and sulfonylnitrenes (2.5). d-Elimination

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