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Base-induced reactions of N-substituted dibenzylamine N-oxides and related compounds: a novel aziridine forming reaction

✍ Scribed by Takayama, Hiroaki; Nomoto, Takashi

Book ID
120333792
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
200 KB
Volume
7
Category
Article
ISSN
0022-4936

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## Abstract A new process for the homolytic acylation of protonated heteroaromatic bases is described; an N‐oxyl radical (PINO) generated from __N__‐hydroxyphthalimide by air oxygen and Co(II) abstracts a hydrogen atom from an aldehyde. The resulting nucleophilic acyl radical adds to a heteroaromat