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Base-Induced Decomposition of Alkyl Hydroperoxides in the Gas Phase. Part 3. Kinetics and Dynamics in HO − + CH 3 OOH, C 2 H 5 OOH, and tert -C 4 H 9 OOH Reactions †

✍ Scribed by Kato, Shuji; Ellison, G. Barney; Bierbaum, Veronica M.; Blanksby, Stephen J.

Book ID: 126033589
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 391 KB
Volume: 112
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp800702z

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✍ Maria Schlangen; Detlef Schröder; Helmut Schwarz 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB 👁 2 views

## Abstract The reactions of small saturated hydrocarbons by gaseous nickel cations NiX^+^ (X=F, Cl, Br, I) are investigated by means of electrospray ionization mass spectrometry. The halide cations are obtained from solutions of the corresponding Ni^II^ salts in water or methanol as solvents. NiF^