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Base hydrolysis of tris(acetylacetonato)metal(III) complexes involving technetium and ruthenium

✍ Scribed by A. Mutalib; T. Omori; K. Yoshihara

Book ID: 112697736
Publisher: Springer
Year: 1993
Tongue: English
Weight: 428 KB
Volume: 170
Category: Article
ISSN: 1588-2780
DOI: 10.1007/bf02134577

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## Abstract Molecular‐orbital calculations have been performed for the conjugate base __cis__‐[Co(NH~3~)~4~(NH~2~)Cl]^+^ and __trans__‐[M(NH~3~)~4~(NH~2~)Cl]^+^ (M = Cr^III^, Co^III^, and Rh^III^), the hexacoordinated intermediates __cis‐__ and __trans__‐[Co(NH~3~)~4~(NH~2~)…Cl]^+^, the square‐pyra