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Base hydrolysis of [Rh(NH3)5OCOR]2+ ions: Influence of polar and steric requirements of the R groups on the reaction mechanism

✍ Scribed by Fabrizio Monacelli


Book ID
118906400
Publisher
Elsevier Science
Year
1967
Weight
468 KB
Volume
29
Category
Article
ISSN
0022-1902

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On the mechanism of the Hg2+ and base in
✍ David A. Buckingham; Werner Marty; Alan M. Sargeson πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 894 KB

## Acid hydrolysis of the ester function in A-( -)589-fi2-(RR)-[Co (trien) (glyOEt)C1I2+ (( -)-1) produces optically pure A-( -)589$2-(RR)-[CO (trien) (glyOH)C1I2+ (( -)-4). Hg2+ induced removal of chloride in (-)-4 follows the rate law kobs=kHg [Hg2+] with kHg=(1.36+0.03)x 1 0 -2 ~-l s -' , 25",