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Base-Free Oxidative Homocoupling of Arylboronic Esters.

✍ Scribed by Hiroto Yoshida; Yasuhito Yamaryo; Joji Ohshita; Atsutaka Kunai

Book ID: 101944559
Publisher: John Wiley and Sons
Year: 2003
Weight: 116 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200320109

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Base-free oxidative homocoupling reaction of arylboronic esters has been found to proceed using a catalytic amount of a palladium-1,3-bis(diphenylphosphino)propane (DPPP) complex under an oxygen atmosphere, affording a variety of biaryls in modest to excellent yields. Even arylboronic esters bearing

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