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Base-catalyzed rearrangement of 4-methyl-4-acetoxy-2,6-di-tert-butyl-2,5-cyclohexadienone

✍ Scribed by Chasar, Dwight W.


Book ID
127103601
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
277 KB
Volume
45
Category
Article
ISSN
0022-3263

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Photolysis of 2,6 di-tert-butyl-4-tert-b
✍ J. Pilaǎ; J. Kovářová; J. Pospíšil 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB

## Abstract The photolysis of a heptane solution of 2,6‐di‐__tert__‐butyl‐4‐__tert__‐butylperoxy‐4‐methyl‐ 2,5‐cyclohexadienone (1) with light of 360–480 nm in the presence of 2,6‐di‐__tert__‐butyl‐4‐methylphenol or 2,4,6‐tri‐__tert__‐butylphenol gives rise to their corresponding phenoxyls in a rea