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Base catalysed rearrangements of α-ketols

✍ Scribed by Yehuda Mazur; Manasse Nussim

Publisher
Elsevier Science
Year
1961
Tongue
French
Weight
225 KB
Volume
2
Category
Article
ISSN
0040-4039

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## Abstract The BF~3~ · Et~2~O‐ and the CH~3~SO~3~H‐catalysed rearrangements of 10 α‐vinylcyclobutanones have been examined. With little acid, the β,β‐dialkyl derivatives **1** were transformed into linear dienones **2** and **3**; with more acid, they were converted into cyclopentenones **4** by _