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Base-catalysed isomerization of 7-(methoxycarbonyl)-1,3,5-cycloheptatriene

✍ Scribed by A. W. Zwaard; M. D. Prins; H. Kloosterziel

Book ID
104588607
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
294 KB
Volume
103
Category
Article
ISSN
0165-0513

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Protonated 1,3,5-cycloheptatriene and 7-
Protonated 1,3,5-cycloheptatriene and 7-alkyl-1,3,5-cycloheptatrienes in the gas phase: ring contraction to the isomeric alkylbenzenium ions
✍ Mormann, Michael; Kuck, Dietmar πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 298 KB

1,3,5-Cycloheptatriene (1) and various 7-alkyl-1,3,5-cycloheptatrienes (3, 6, 9, 13, and 16-19) were subjected to gas-phase protonation under and conditions and the MIKE spectra of their [ M + H ] ' ions CI(CH 4 ) CI(iC 4 H 10 ) were measured. Loss of from the parent ion [ 1 + H ] ' and almost exclu