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Base-catalysed alkylations and conjugated additions of α-cyanoenamines : A method for chain extension at the β-carbon of tertiary amides

✍ Scribed by Brigitte Lesur; José Toye; Marianne Chantrenne; Léon Ghosez


Book ID
104237851
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
212 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis


Anions derived fromcl-cyan oenamines which are readily available from tertiary ami- des, react at the y-carbon atom with alkylating agents and cl-enones.

In 1975, two of us described(') a practical one-pot procedure for the conversion of tertiary amides J. into a-cyanoenamines 2.