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Base- and Co(II)-Catalyzed Ring-Opening Reactions of Perhydrooxireno[2,3- d ][1,2]dioxines: An Efficient Route to 4-Hydroxy-2,3-epoxy-ketones

โœ Scribed by Greatrex, Ben W.; Jenkins, Natalie F.; Taylor, Dennis K.; Tiekink, Edward R. T.


Book ID
126215967
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
106 KB
Volume
68
Category
Article
ISSN
0022-3263

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Rhodium(II) acetate-catalyzed reaction o
โœ Edward C. Taylor; Huw M.L. Davies ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

Rhodium(I1) acetate-catalyzed decomposition of ethyl 2-diazo-3oxopent-4-enoates results in the formation of either 4-aryl-2-hydroxynaphthoates or 6,y-unsaturated esters. In the latter transformation, the dianion of 4-(diethylphosphono)acetoacetate functions as a propionate homoenolate equivalent.