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Barriers to rotation of 9-substituents in 9-hydroxy-, 9-amino-, and 9-methyltriptycenes

โœ Scribed by Imashiro, Fumio; Hirayama, Kei; Terao, Takehiko; Saika, A.


Book ID
126871386
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
565 KB
Volume
109
Category
Article
ISSN
0002-7863

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Radical anions from a series of 9-substituted-and 9,1O-disubstituted-2,6-dinitro-and 2,7-dinitro-9,10-dihydro-9,10ethanoanthracenes were investigated by EPR spectroscopy at 25 "C. In the case of radical anions of compounds with nitro groups in both the 2-and &positions, hyperfine coupling constants