Barriers to rotation and rotamer preferences in acyclic hydrocarbons
β Scribed by C. Hackett Bushweller; Warren G. Anderson
- Book ID
- 104237065
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 170 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The electronic states and barriers to internal rotation in allene (**1a**), 1βsilaallene (**2a**), and 2βsilaallene (**3a**) are investigated computationally using __ab__β__initio__ molecular orbital methods. Planar geometries with twoβ, threeβ, and fourβΟβelectron configurations have b
## Abstract Activation parameters for the hindered rotation in some dimethylamino substituted azoles are reported and the effects of various ring systems and substituents on the barrier are discussed. Possible errors in Ξ__H__β and Ξ__S__β are investigated.