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Barriers to internal rotation around the glycosidic bond of nucleosidess with symmetric aglycones

✍ Scribed by H. von Voithenberg; A. Skrzelewski; J.C. Jochims; W. Pfleiderer

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
212 KB
Volume
15
Category
Article
ISSN
0040-4039

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Unusually low barriers to rotation around carbon-carbon double bonds have recently been reported by two groups (1,Z). The publication by Gompper and Schaefer (3) of the preparation of some nitroketene mercaptale and related compounds prompts us to give a preliminary report on the observation of low

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Calculations of the barrier to internal rotation in ethyl flouride: A comparison with ethane
✍ William E. Palke πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 406 KB

Sasis sets. Minimum basis set calculations predict the barrier in ethyl fluoride to be 0.5 kcd/mole smaller than the ethzne barrier. Extended basjs set cdcufations give barriers of 3.4 and 3.3 kcal/mole for ethyl fluoride and ethane. These results are in better ;igrecment with the espcrimcntal value